cis-1-Aminoindan-2-ol in Asymmetric Syntheses
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چکیده
منابع مشابه
cis-2-(4-Methoxyphenyl)-4-methyl-1,2-dihydronaphthalen-1-ol
The stereochemistry and regiochemistry of the title compound, C18H18O2, were determined by the X-ray analysis. There are two independent mol-ecules in the asymmetric unit in which the dihedral angles between the benzene rings are 88.31 (4) and 86.27 (4)°. The cyclo-hexene rings are in half-chair conformations. In the crystal, O-H⋯O hydrogen bonds link alternating types of mol-ecules into chains...
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Enantioselective reductive desymmetrization of glutarimides has been achieved employing an oxazaborolidine catalyst derived from cis-1-amino-indan-2-ol. The reaction was found to proceed through a stereoablative process that upgraded the enantioselectivity of an intermediate hydroxy-lactam. The reaction was generally tolerant of a number of substituents in the 4-position, giving enantiomeric ex...
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ژورنال
عنوان ژورنال: Synthesis
سال: 1998
ISSN: 0039-7881,1437-210X
DOI: 10.1055/s-1998-2092